The electronic interactions between the Li atoms and the Si atoms can be seen in the partial density of states (pDOS) plots for the systems plotted in Fig. 14. where similar to the single Li decorated systems, significant overlap between the Li and the Si orbitals can be seen from -3 eV to -1 eV and after the Fermi level from 1 eV in the SV silicene system. Extended overlap can be seen after the Fermi level and it can be observed that the region of overlap is greater in the case of the Li double side decorated SV silicene system similar to the single Li decoration SV silicene system, which substantiates the higher binding energies seen in this system.